Complete Solutions and Summary of Organic Chemistry – Some Basic Principles and Techniques – NCERT Class 11, Chemistry, Chapter 8 – Summary, Questions, Answers, Extra Questions
Overview of general organic chemistry definitions, classification, nomenclature (IUPAC system), electronic effects, types of organic reactions, reaction mechanisms (homolytic and heterolytic bond cleavage), reactive intermediates (carbocations, free radicals, carbanions), and techniques in organic chemistry.
Part A (1 mark short: 1-2 sentences), B (4 marks medium ~6 lines/detailed explanation), C (8 marks long: Detailed with examples/derivations/graphs). Based on NCERT Exercises 8.1-8.6 (from PDF; extended to 40+ assuming full chapter).
Part A: 1 Mark Questions (Short Answers - From NCERT Exercises)
8.1 Sigma pi in HC≡CCH=CHCH3?
1 Mark Answer: σC-C 4; σC-H 6; πC=C 1; πC≡C 2.
8.2 Hybrid each C in CH3Cl?
1 Mark Answer: sp3.
8.3 Hybrid shape H2C=O?
1 Mark Answer: sp2 trigonal planar.
8.4 Expand CH3CH2COCH2CH3?
1 Mark Answer: CH3-CH2-C(=O)-CH2-CH3.
8.5 Condensed HOCH2CH2CH2CH(CH3)CH(CH3)CH3?
1 Mark Answer: HO(CH2)3CH(CH3)CH(CH3)2.
8.6 Expand bond-line zigzag with Br?
1 Mark Answer: CH3CHBrCH2CH3.
8.30 What vital force?
1 Mark Answer: Life force organic synthesis.
8.31 Wohler synthesized?
1 Mark Answer: Urea from ammonium cyanate.
8.32 Functional group?
1 Mark Answer: Characteristic props atom group.
8.33 Homologous series?
1 Mark Answer: Same functional differ CH2.
8.34 IUPAC alkane?
1 Mark Answer: -ane suffix carbon num.
Part B: 4 Marks Questions (Medium Length ~6 Lines - From NCERT)
8.1 Vital force theory reject.
4 Marks Answer: Berzelius proposed vital force plant animal organic; Wohler 1828 urea NH2CONH2 from inorganic NH4CNO heat; Kolbe acetic; Berthelot methane; lab synthesis possible.
8.2 Tetravalence C shapes.
4 Marks Answer: C 4 valence covalent; sp3 tet CH4; sp2 tri C2H4; sp lin C2H2; hybrid s char inc EN dec length inc strength.
8.3 Pi bonds features.
4 Marks Answer: Sideways p parallel planar; rotation restrict; cloud above below reactive attack.
8.4 Structural formulas types.
4 Marks Answer: Complete dashes bonds; condensed subscripts; bond-line zig-zag no C H; 3D wedge solid out dashed away.
8.5 Molecular models.
4 Marks Answer: Framework bonds; ball-stick atoms bonds springs; space-filling van der Waals no bonds; computer graphics.
8.6 Classification organic.
4 Marks Answer: Acyclic aliphatic open; cyclic alicyclic homo hetero, aromatic benzenoid non hetero; functional groups; homologous CH2.
8.7 IUPAC alkanes straight.
4 Marks Answer: -ane suffix num C meth eth prop etc; CnH2n+2; ex C5H12 pentane.
8.8 Branched alkanes nomen.
4 Marks Answer: Longest chain parent; alkyl pre; low num; alpha order; ex 3-methyloctane.
8.9 Alkyl groups branched.
4 Marks Answer: Iso (CH3)2CH-; sec CH3CH2CH(CH3)-; tert (CH3)3C-; neo (CH3)3CCH2-.
8.10 Trivial names.
4 Marks Answer: Origin props; ex formic ant; acetic vinegar; urea urine; still used complex.
Part C: 8 Marks Questions (Detailed Long Answers - From NCERT)
8.1 History organic chem Wohler Kolbe.
8 Marks Answer: 1780 distinguish organic life inorganic mineral; Berzelius vital force; Wohler1828 urea NH4CNO to NH2CONH2 reject; Kolbe1845 acetic; Berthelot1856 methane; electronic covalent modern. Deriv: Lab from inorganic. Ex: Urea white crystal. Graph: None. Ties: Catenation. Advanced: Synth total. Errors: Vital complete? Enzymes. Real: Fertilizer. Historical: 200 years.
8.2 Tetravalence hybrid shapes bonds.
8 Marks Answer: C config hybrid sp3 tet 109.5 CH4; sp2 tri 120 C2H4; sp lin 180 C2H2; s char inc EN short strong; pi sideways planar restrict rot reactive. Deriv: Orbital mix. Ex: Ethene double sigma pi. Graph: Overlap. Ties: Structures. Advanced: Bent. Errors: All single sp3? No. Real: Addition alkene. Historical: VBT.
8.3 Structural reps complete condensed bond-line 3D models.
8 Marks Answer: Complete dashes lone; condensed sub no dashes; bond-line zig no C H hetero terminals CH3; 3D wedge solid out dash away; models framework ball-stick space-filling computer. Deriv: Simplify. Ex: 2-bromobutane forms. Graph: Fig8.1. Ties: Nomen. Advanced: Mol graphics. Errors: Bond-line cyclic close. Real: Drug design. Historical: Fischer.
IUPAC -ane pre; branched longest low alpha; alkyl Me Et iso neo sec tert; trivial common.
Key Formulas
Alkanes CnH2n+2; alkyl CnH2n+1; sigma pi count.
Ponder
Organic C central; structures understand; class function; nomen systematic; shapes hybrid.
Mnemonics: Hybrids "Silly People Sing" (sp3 sp2 sp). Class "All Cats Are Friendly Humans" (Acyclic Cyclic Aromatic Functional Homologous). Prefixes "My Elephant Plays Basketball" (Meth Eth Prop But). Branched "I See New Stars Tonight" (Iso Sec Neo Sec Tert). History "Very Well Known Brothers" (Vital Wohler Kolbe Berthelot).
Tip: Draw name practice; classify groups; count bonds; convert reps.
2 attempts on CBSE Class 11 Annual Assessment quizzes
f scored 4/10 on Accountancy (Class 11) Subhash scored 1/10 on Sets and Venn Operations f scored 4/10 on Accountancy (Class 11) Subhash scored 1/10 on Sets and Venn Operations
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